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138163-08-3 N-Cbz-Piperidine-4-carbaldehyde

138163-08-3 N-Cbz-Piperidine-4-carbaldehyde

4-FORMYL-N-CBZ-PIPERIDINE Basic information 4-FORMYL-N-CBZ-PIPERIDINE Chemical Properties Safety Information MSDS Information 4-FORMYL-N-CBZ-PIPERIDINE Usage And Synthesis 4-FORMYL-N-CBZ-PIPERIDINE Preparation Products And Raw materials Upstream information Ethyl 1-Cbz-Piperidine-4- Carboxylate;...

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Product Details:

4-FORMYL-N-CBZ-PIPERIDINE Basic information

Product Name:

4-FORMYL-N-CBZ-PIPERIDINE

Synonyms:

4-FORMYL-N-CBZ-PIPERIDINE; 4-FORMYL-PIPERIDINE-1-CARBOXYLIC ACID BENZYL ESTER; BUTTPARK 92\50-59; BENZYL 4-FORMYLTETRAHYDRO-1(2H) -PYRIDINECARBOXYLATE; N-CBZ-4-PIPERIDINYLCARBOXALDEHYDE; N-CBZ-4-FORMYLPIPERIDINE; Piperidine-4-carboxaldehyde, N-CBZ protected; Benzyl 4-formyltetrahydro-1(2H) -pyridinecarboxylate, 90+%

CAS:

138163-08-3

MF:

C14H17NO3

MW:

247.29

EINECS:


Product Categories:

Carbonyl Compounds; Heterocycles

Mol File:

138163-08-3.mol

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4-FORMYL-N-CBZ-PIPERIDINE Chemical Properties

Density:

1.221g/cm3

Boiling Point:

384.5ºC at 760mmHg

Flash Point:

186.3ºC

Refractive Index:

1.593

Vapor Pressure:

4.07E-06mmHg at 25°C

CAS DataBase Reference

138163-08-3(CAS DataBase Reference)


Safety Information

Hazard Codes

Xi

Risk Statements

36/37/38

Safety Statements

26-36/37/39-24/25

Hazard Note

Irritant

Hs code

2933399090


MSDS Information


4-FORMYL-N-CBZ-PIPERIDINE Usage And Synthesis

Intermediate as

159752-10-0 MK677(mesylate salt)

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Synthesis route

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Reference:

1. Fang, Xinqin; Garvey, David S.; Gaston, Ricky D.; Lin, Chia-En; Ranatunga, Ramani R.; Richardson, Stewart K.; Wang, Tiansheng; Wang, Weiheng; Wey, Shiow-Jyi Patent: US2003/203915 A1, 2003

2. NEUROSEARCH A/S Patent: WO2007/93603 A1, 2007 ; Location in patent: Page/Page column 15 ; WO 2007/093603 A1


image007_副本.jpg

Reference:

1. Amici, M De; Froelund, B; Hjeds, H; Krogsgaard-Larsen, P European Journal of Medicinal Chemistry, 1991 , vol. 26, # 6 p. 625 – 631

2. ELI LILLY AND COMPANY Patent: WO2004/14900 A1, 2004 ; Location in patent: Page 48-49 ; WO 2004/014900 A1


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Reference:

Chinese Chemical Letters, vol. 23, # 6 p. 661 – 664


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Reference:

Tetrahedron Letters, vol. 48, # 2 p. 199 - 202


4-FORMYL-N-CBZ-PIPERIDINE Preparation Products And Raw materials


Upstream information

Ethyl 1-Cbz-Piperidine-4- Carboxylate; Methyltriphenylphosphonium bromide; Oxalyl Chloride; 4-Fluorophenylhydrazine hydrochloride; 1-Benzyl 4-methyl piperidine-1, 4-dicarboxylate; phenylhydrazine; benzyl 4-carbonochloridoylpiperidine-1-carboxylate; Dess-Martin periodinane; 1-Cbz-4-Piperidinecarboxaldehyde; Isonipecotic acid;


Downtream information

1-methylspiro[2H-indole-3, 4'-piperidine]; benzyl 4-benzoylpiperidine-1-carboxylate; 3-(1-((Benzyloxy) carbonyl) piperidin-4-yl) propanoic acid; 6-(tert-Butoxycarbonyl) -6-azaspiro[2.5] octane-1-carboxylic acid; tert-butyl spiro[2H-indole-3, 4'-piperidine] -1-carboxylate; benzyl 9-oxo-3-azaspiro[5.5] undec-10-ene-3-carboxylate; benzyl spiro[indole-3, 4'-piperidine] -1'-carboxylate; tert-Butyl 9-oxo-3-azaspiro[5.5] undecane-3-carboxylate; 2-amino-2-methyl-N-[(2R) -1-(1-methylsulfonylspiro[2H-indole-3,4'-piperidine] -1'-yl) -1-oxo-3-phenylmethoxypropan-2-yl] propanamide; 3-Azaspiro[5.5] undecan-9-one;


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