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718-08-1 Ethyl 3-oxo-4-phenylbutanoate

718-08-1 Ethyl 3-oxo-4-phenylbutanoate

3-OXO-4-PHENYL-BUTYRIC ACID ETHYL ESTER Basic information 3-OXO-4-PHENYL-BUTYRIC ACID ETHYL ESTER Chemical Properties Safety Information 3-OXO-4-PHENYL-BUTYRIC ACID ETHYL ESTER Usage And Synthesis 3-OXO-4-PHENYL-BUTYRIC ACID ETHYL ESTER Preparation Products And Raw materials Related Product...

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Product Details:

3-OXO-4-PHENYL-BUTYRIC ACID ETHYL ESTER Basic information

Product Name:

3-OXO-4-PHENYL-BUTYRIC ACID ETHYL ESTER

Synonyms:

3-OXO-4-PHENYL-BUTYRIC ACID ETHYL ESTER;3-keto-4-phenyl-butyric acid ethyl ester;ethyl 3-oxo-4-phenylbutanoate;ethyl 3-oxo-4-phenyl-butanoate;4-Phenyl-3-oxobutanoic acid ethyl ester;Ethyl 4-phenylacetoacetate;Benzenebutanoic acid, b-oxo-, ethyl ester;b-Oxo-benzenebutanoic acid ethyl ester

CAS:

718-08-1

MF:

C12H14O3

MW:

206.24

EINECS:


Product Categories:


Mol File:

718-08-1.mol

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3-OXO-4-PHENYL-BUTYRIC ACID ETHYL ESTER Chemical   Properties

Boiling point

290℃

density

1.091

Boiling   Point:

290ºC

refractive index

1.054-1.059

Fp

124℃


Safety Information

Risk Statements

36/37/38

Safety Statements

26-36/37/39

Hs code

2918300090


3-OXO-4-PHENYL-BUTYRIC ACID ETHYL ESTER Usage And   Synthesis

Intermediate ase


Synthsis route

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Reference:

1. Lager, Erik; Nilsson, Jakob; stergaard Nielsen, Elsebet; Nielsen, Mogens; Liljefors,   Tommy; Sterner, Olov Bioorganic and Medicinal Chemistry, 2008 , vol. 16, # 14 p. 6936 - 6948

2. Terai, Takuya; Kikuchi, Kazuya; Iwasawa, Shin-Ya; Kawabe, Takao; Hirata, Yasunobu; Urano, Yasuteru; Nagano, Tetsuo Journal of the American Chemical Society, 2006 , vol. 128, # 21 p. 6938 - 6946

3. J. Uriach and Cia, S.A. Patent: US5827863 A1, 1998 ; US 5827863 A

4. Takasago International Corporation Patent: US5945559 A1, 1999

5. Shimkin; Shirinian; Mailian; Lonshakov; Gorokhov; Krayushkin Russian Chemical Bulletin, 2011 , vol. 60, # 1 p. 139 - 142

6. Nakagawa, Hidehiko; Ohyama, Ryo; Kimata, Ayako; Suzuki, Takayoshi; Miyata, Naoki Bioorganic and Medicinal Chemistry Letters, 2006 , vol. 16, # 23 p. 5939 - 5942

7. Bioorganic and Medicinal Chemistry, vol. 7, # 6 p. 991 - 1002

8. Bioorganic and Medicinal Chemistry Letters, vol. 16, # 10 p. 2796 - 2799

9. Journal of the American Chemical Society, vol. 66, p. 1286

10. WO2010/66682 A1, ; Page/Page column 195; 222 ; WO 2010/066682 A1


image003_副本.jpg

Reference:

Jeyakumar, Kandasamy; Chand, Dillip Kumar   Synthesis, 2008 , # 11 p. 1685 - 1687


image005_副本.jpg

Reference:

Rao, D. Chandra; Reddy, D. Kumar; Shekhar;   Chinababu; Rao, Ch. Bhujanga; Venkateswarlu Indian Journal of Chemistry -   Section B Organic and Medicinal Chemistry, 2014 , vol. 53, # 3 p. 356 - 358


image009_副本.jpg

Reference:

Journal of Organic Chemistry, , vol. 54, # 17   p. 4229 - 4231


3-OXO-4-PHENYL-BUTYRIC ACID ETHYL ESTER Preparation   Products And Raw materials


Related Product Information

3-OXO-4-P-TOLYL-BUTYRIC ACID ETHYL ESTER 4-(4-FLUORO-PHENYL)-3-OXO-BUTYRIC ACID ETHYL ESTER 4-(3,4-DIMETHOXY-PHENYL)-3-OXO-BUTYRIC ACID ETHYL ESTER 4-(3,4-DICHLORO-PHENYL)-3-OXO-BUTYRIC ACID ETHYL ESTER 4-(4-CHLORO-PHENYL)-3-OXO-BUTYRIC ACID ETHYL ESTER 4-(3-CHLORO-PHENYL)-3-OXO-BUTYRIC ACID ETHYL ESTER 4-(2-METHOXY-PHENYL)-3-OXO-BUTYRIC ACID ETHYL ESTER 4-(4-BROMO-PHENYL)-3-OXO-BUTYRIC ACID ETHYL ESTER ETHYL 2,4-DIPHENYLACETOACETATE 4-(3-FLUORO-PHENYL)-3-OXO-BUTYRIC ACID ETHYL ESTER 3-OXO-4-M-TOLYL-BUTYRIC ACID ETHYL ESTER 4-(4-METHOXY-PHENYL)-3-OXO-BUTYRIC ACID ETHYL ESTER ETHYL-2-(METHYLETHYL)-3-OXO-4-PHENYLBUTANOATE 4-(2-BROMO-PHENYL)-3-OXO-BUTYRIC ACID ETHYL ESTER ETHYL 4-(2-NITROPHENYL)ACETOACETATE 4-(3-NITRO-PHENYL)-3-OXO-BUTYRIC ACID ETHYL ESTER 4-(3-METHOXY-PHENYL)-3-OXO-BUTYRIC ACID ETHYL ESTER 4-(4-NITRO-PHENYL)-3-OXO-BUTYRIC ACID ETHYL ESTER


Upstream information

Ethyl Potassium Malonate; phenylacetone; sodium ethoxide; Ethanol; hydrogen chloride; Ethyl acetoacetate; styrene oxide; N-methoxy-N-methyl-2-phenylacetamide; 1-(1H-imidazol-1-yl)-2-phenylethan-1-one; thiourea;


Downtream information

2-phenylacetamide; (2S,3R)-3-Amino-2-hydroxy-4-phenylbutyric acid; ethyl (2R,3S)-2-chloro-3-hydroxy-4-phenylbutyrate; 6-benzyl-5-propan-2-yl-2-sulfanylidene-1H-pyrimidin-4-one; 6-benzyl-2-sulfanylidene-1H-pyrimidin-4-one; 6-benzyl-5-iodo-1H-pyrimidine-2,4-dione; phenylacetone; Phenylacetic acid ethyl ester; 4-hydroxy-3-methyl-2-phenylcyclopent-2-en-1-one; 1,3-Dihydroxynaphthalene


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