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1072-84-0 1H-imidazole-4-carboxylic Acid

1072-84-0 1H-imidazole-4-carboxylic Acid

1H-Imidazole-4-carboxylic acid Basic information 1H-Imidazole-4-carboxylic acid Chemical Properties Safety Information 1H-Imidazole-4-carboxylic acid Usage And Synthesis 1H-Imidazole-4-carboxylic acid Preparation Products And Raw materials Upstream information (2E)-3-(1H-Imidazol-4-yl)acrylic...

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Product Details:

1H-Imidazole-4-carboxylic acid Basic information

Product Name:

1H-Imidazole-4-carboxylic    acid

Synonyms:

4-hydroxy imizodale;Imidazol-4-carboxylic acid;1H-Imidazole-5-carboxylic acid 98%;1H-Imidazole-4-carboxylic acid,98%;3H-Imidazole-4-carboxylic acid, 5-Carboxy-1H-imidazole, 1H-Imidazole-4-carboxylic acid, 4-Carboxy-1H-imidazole;4-IMIDAZOLECARBOXYLIC ACID 98;1H-IMidazole-4;1H- iMidazole-4- forMic aci

CAS:

1072-84-0

MF:

C4H4N2O2

MW:

112.09

EINECS:

214-017-8

Product Categories:

blocks;Carboxes;Imidazoles;Imidazoles, Pyrroles, Pyrazoles, Pyrrolidines;pharmacetical;Heterocyclic Compounds;Heterocycle;Imidaxoles;Carboxylic Acids;Imidazoles & Benzimidazoles;Building Blocks;Heterocyclic Building Blocks

Mol File:

1072-84-0.mol

image001.gif


1H-Imidazole-4-carboxylic acid Chemical Properties

Appearance    :

White powder

Density:

1.524 g/cm3

Melting    Point:

243-245ºC

Boiling    Point:

495ºC at 760 mmHg

Flash    Point:

253.2ºC

Storage   Condition:

Refrigerator

Vapor   Pressure:

1.29E-10mmHg at 25°C

CAS DataBase Reference

1072-84-0(CAS    DataBase Reference)


Safety Information

Hazard Codes 

Xi

Risk Statements 

36/37/38

Safety Statements 

26-36-37/39

WGK Germany 

3

RTECS 

NI4001000

Hazard Note 

Irritant

HazardClass 

IRRITANT

Hs code

2933290090


1H-Imidazole-4-carboxylic acid Usage And Synthesis

Chemical Properties

Gray or tan powder

Intermediate as

33125-97-2 Etomidate,86347-14-0 Medetomidine, 5377-20-8 Metomidate, 113775-47-6 Dexmedetomidine

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Synthesis route

image011_副本.jpg

Reference:

Sloboda-Rozner, Dorit; Witte, Peter; Alsters, Paul L.; Neumann, Ronny Advanced Synthesis and Catalysis,2004,vol.346,#2-3 p.339 -345

image013_副本.jpg

Reference:

Gadakh, Amol V.; Chikanna, Dinesh; Rindhe,Sahebrao S.; Karale, Bhausaheb K.Synthetic Communications,2012,vol.42, # 5 p. 658 - 666

image015_副本.jpg

Reference:

Davis, Dwight P.; Kirk, Kenneth L.; Cohen, Louis A. Journal of Heterocyclic Chemistry, 1982 , vol. 19, p. 253 - 256


1H-Imidazole-4-carboxylic acid Preparation Products And Raw materials

Preparation Products

1-Trityl-1H-imidazole-4-carboxylic    acid

Raw materials

Sulfuric    acid-->Acetic    anhydride-->Triethyl    orthoformate-->Anisole-->4,5-Imidazoledicarboxylic    acid-->Diaminomaleonitrile


Upstream information

(2E)-3-(1H-Imidazol-4-yl)acrylic acid; 5-bromo-1H-imidazole; Dimethylamine; formyl acetate; methanol; N-phenyl-1H-imidazole-5-carboxamide;diazomethane; Iodine; 4,5-Imidazoledicarboxylic acid; Ethanol;


Downtream information

1H-imidazole-5-carbaldehyde; cis-urocanic acid; 1,3-dimethylimidazol-1-ium-4-carboxylate; 2,4,5-Triiodo-1H-imidazole; Diimidazo[1,5-a:1,5-d]pyrazine-5,10-dione, dihydrochloride; 1H-imidazole-5-carbonyl chloride; Methyl 4-imidazolecarboxylate; ethyl 1H-imidazole-5-carboxylate; 1H-imidazole; imidazol-4-ylacetic acid

 

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