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17325-26-7 Methyl 4-imidazolecarboxylate

17325-26-7 Methyl 4-imidazolecarboxylate

Methyl 4-imidazolecarboxylate Basic information Methyl 4-imidazolecarboxylate Chemical Properties Safety Information Methyl 4-imidazolecarboxylate Usage And Synthesis Methyl 4-imidazolecarboxylate Preparation Products And Raw materials Upstream information 1,2,3,4-Tetrahydro-1-naphthol; benzyl...

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Product Details:

Methyl 4-imidazolecarboxylate Basic information

Product Name:

Methyl    4-imidazolecarboxylate

Synonyms:

RARECHEM AL BF 0762;METHYL IMIDAZOLE-4-CARBOXYLATE;METHYL 4-IMIDAZOLECARBOXYLATE;Methyl 1H-imidazole-4-carboxylate;1H-Imidazole-4-carboxylic acid methyl ester;3H-Imidazole-4-carboxylic acid methyl ester;Methyl 4-imidazolecarboxylate,98%;Methyl 4-imidazolecarboxylate ,99%

CAS:

17325-26-7

MF:

C5H6N2O2

MW:

126.11

EINECS:

1312995-182-4

Product Categories:

pharmacetical;Heterocyclic Compounds;Heterocycle;Building Blocks;Heterocyclic Building Blocks;Imidazoles;Building Blocks;Chemical Synthesis;Heterocyclic Building Blocks

Mol File:

17325-26-7.mol

image001.gif


Methyl 4-imidazolecarboxylate Chemical Properties

form 

Crystalline Powder

color 

White

Appearance:

White crystalline powder

Density:

1.275g/cm3

Melting    Point:

154-156ºC

Boiling    Point:

318.2ºC at 760mmHg

Flash    Point:

146.2ºC

Refractive   Index:

1.53

Vapor   Pressure:

0.000368mmHg at 25°C

CAS DataBase Reference

17325-26-7(CAS    DataBase Reference)


Safety Information

Hazard Codes 

Xi

Risk Statements 

36/37/38

Safety Statements 

26-36

WGK Germany 

3

HazardClass 

IRRITANT

Hs code

2933290090


Methyl 4-imidazolecarboxylate Usage And Synthesis

Chemical Properties

White crystalline powder

Intermediate as

86347-14-0 Medetomidine, 5377-20-8    Metomidate, 113775-47-6 Dexmedetomidine

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Synthesis route

image009_副本.jpg

Reference:

1. Bischoff, Alexander; Subramanya, Hosahalli; Sundaresan, Kumar; Sammeta, Srinivasa Raju; Vaka, Anil Kumar Patent: US2010/160323 A1, 2010 ; Location in patent: Page/Page column 23-24 ; US 20100160323 A1
2. Moutevelis-Minakakis, Panagiota; Papavassilopoulou,Eleni; Michas, George; Georgikopoulou, Kalliopi; Ragoussi, Maria-Eleni; Neophytou, Niki; Zoumpoulakis, Panagiotis; Mavromoustakos, Thomas;   Hadjipavlou-Litina, Dimitra Bioorganic and Medicinal Chemistry, 2011 , vol. 19, # 9 p. 2888 - 2902
3. US5034539 A1, ; US 5034539 A

image011_副本.jpg

Reference:

Kress, Thomas J. Journal of Organic    Chemistry, 1985 , vol. 50, # 17 p. 3073 - 3076


Methyl 4-imidazolecarboxylate Preparation Products And Raw materials


Upstream information

1,2,3,4-Tetrahydro-1-naphthol; benzyl alcohol; methanol; propylamine; diazomethane; benzyl bromide; 2-Iodopropane; Methyl 4-imidazolecarboxylate; 1-Iodopentane; 1-Iodopropane;


Downtream information

Methyl 4-imidazolecarboxylate; methyl 1-propylimidazole-4-carboxylate; methyl 3-(1,2,3,4-tetrahydronaphthalen-1-yl)imidazole-4-carboxylate; methyl 5-bromo-1H-imidazole-4-carboxylate; Methyl 1-trityl-1H-imidazole-4-carboxylate; 1H-imidazole-5-carboxamide; imidazole-4-methanol; 1H-imidazole-5-carbohydrazide; methyl 1-propan-2-ylimidazole-4-carboxylate; N-propyl-1H-imidazole-5-carboxamide

 

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