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26218-75-7 Methyl 6-bromopyridine-2-carboxylate

26218-75-7 Methyl 6-bromopyridine-2-carboxylate

6-BROMOPYRIDINE-2-CARBOXYLIC ACID METHYL ESTER Basic information 6-BROMOPYRIDINE-2-CARBOXYLIC ACID METHYL ESTER Chemical Properties Safety Information 6-BROMOPYRIDINE-2-CARBOXYLIC ACID METHYL ESTER Usage And Synthesis 6-BROMOPYRIDINE-2-CARBOXYLIC ACID METHYL ESTER Preparation Products And Raw...

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Product Details:

6-BROMOPYRIDINE-2-CARBOXYLIC ACID METHYL ESTER Basic information

Product Name:

6-BROMOPYRIDINE-2-CARBOXYLIC    ACID METHYL ESTER

Synonyms:

Methyl    6-bromo-2-pyridinecarboxylate, Methyl 6-bromopicolinate;Methyl-6-bromopyridine-2-carboxylate    ,97%;Methyl 6-bromopicolinate,    2-Bromo-6-(methoxycarbonyl)pyridine;6-broMopyridine-2-Pyridinecarboxylicacid    Methyl ester;2-Pyridinecarboxylicacid,    6-broMo-, Methyl ester;Methyl    6-broMo-2-pyridinecarboxylat;Methyle6-bromopyridine-2-carboxylate;RARECHEM AL BF 0899

CAS:

26218-75-7

MF:

C7H6BrNO2

MW:

216.03

EINECS:

1312995-182-4

Product Categories:

NULL;blocks;Carboxes;Pyridines;Pyridine;Pyridine Series;Boronic Acid

Mol File:

26218-75-7.mol

image001.gif


6-BROMOPYRIDINE-2-CARBOXYLIC ACID METHYL ESTER Chemical Properties

form 

Crystalline Powder or Needles

color 

White to pale pink to pale brown    to yellow

Density:

1.579g/cm3

Melting    Point:

92-96ºC(lit.)

Refractive   Index:

1.554

Storage   Condition:

Keep Cold

Vapor   Pressure:

0.002mmHg at 25°C

CAS DataBase Reference

26218-75-7(CAS    DataBase Reference)


Safety Information

Hazard Codes 

Xi

Risk Statements 

37/38-41

Safety Statements 

26-39

WGK Germany 

3

Hazard Note 

Harmful/Irritant/Keep Cold

Hs code

2933399090


6-BROMOPYRIDINE-2-CARBOXYLIC ACID METHYL ESTER Usage And Synthesis

Chemical Properties

White to off-white solid

Intermediate as

955365-80-7 MK-1775

image003_副本.jpg

Synthesis route

image005_副本.jpg

Reference:

Synthesis, , # 2 art. no. F16609SS, p. 276 -  282

image007_副本.jpg

Reference:

  1. WO2003/84917 A1, ; Page/Page column 26

  2. US2006/235028 A1, ; Page/Page column 32 ; US  20060235028 A1

  3. WO2005/97768 A2, ; Page/Page column 79-80 ; WO  2005/097768 A2

  4. Journal of Organic Chemistry, , vol. 16, p. 1485,1491

image009_副本.jpg

Reference:

Bioorganic and Medicinal Chemistry Letters, , vol. 8, # 16 p. 2117 - 2122


6-BROMOPYRIDINE-2-CARBOXYLIC ACID METHYL ESTER Preparation Products And Raw materials

Raw materials

Ethyl    acetate-->Methanol-->Sulfuric    acid-->Thionyl    chloride-->PETROLEUM    ETHER-->Sodium    carbonate-->Magnesium    sulfate-->Sodium    bicarbonate-->p-Toluenesulfonic    acid-->Magnesium-->6-Bromopicolinic    acid


Upstream information

3,5-Difluorophenylboronic acid; iodomethane; diazomethane; methanol; Methylmagnesium iodide; Tributyl(vinyl)tin; 4-methylquinoline; 2,6-Dibromopyridine; Copper(I) cyanide; 6-Bromopyridine-2-carbaldehyde;


Downtream information

1-(6-Bromo-2-pyridinyl)-2-(4-quinolinyl)ethanone; Methyl 6-(trifluoromethyl)picolinate; 2-(6-bromopyridin-2-yl)propan-2-ol; 6-(Methoxymethyl)-2-pyridinamine;methyl 6-cyanopyridine-2-carboxylate; 6-(4-Fluorophenyl)picolinic acid; (6-bromopyridin-2-yl)methanol; 6-bromopyridine-2-carboxamide; 6-Bromopicolinic acid; methyl 6-ethenylpyridine-2-carboxylate

 

Related Product Information

Picolinic acid Methyl picolinate 5-BROMOPYRIDINE-2-CARBOXYLIC ACID METHYL ESTER 5-Bromonicotinic acid methyl ester, 5-Bromopyridine-3-carboxylic acid methyl ester, Methyl 5-bromonicotinate,5-BROMOPYRIDINE-3-CARBOXYLIC ACID METHYL ESTER 3-AMINO-6-BROMOPYRIDINE-2-CARBOXYLIC ACID METHYL ESTER 2-Bromopyridine -4-carboxylic acid methyl ester 5-BROMOPYRIDINE-2-CARBOXYLIC ACID METHYL ESTER 4-BROMOPYRIDINE-3-CARBOXYLIC ACID METHYL ESTER 5-Bromo-2-Pyridine carboxylic acid methyl ester 3-BROMOPYRIDINE-4-CARBOXYLIC ACID METHYL ESTER 2-Bromo-3-pyridinecarboxylic acid methyl ester methyl 6-bromo-5-[(3-methylbenzyl)oxy]-2-pyridinecarboxylate 6-BROMOPYRIDINE-2-CARBOXYLIC ACID METHYL ESTER methyl 5-(allyloxy)-6-bromo-2-pyridinecarboxylate METHYL 3,6-DIBROMOPICOLINATE methyl 6-bromo-5-methoxy-2-pyridinecarboxylate 6-BROMOPYRIDINE-2-CARBOXYLIC ACID ETHYL ESTER methyl 6-bromo-5-hydroxy-2-pyridinecarboxylate


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