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4792-58-9 Ethyl 5-Methoxyindole-2-Carboxylate

4792-58-9 Ethyl 5-Methoxyindole-2-Carboxylate

ETHYL 5-METHOXYINDOLE-2-CARBOXYLATE Basic information ETHYL 5-METHOXYINDOLE-2-CARBOXYLATE Chemical Properties Safety Information ETHYL 5-METHOXYINDOLE-2-CARBOXYLATE Usage And Synthesis ETHYL 5-METHOXYINDOLE-2-CARBOXYLATE Preparation Products And Raw materials Upstream information Allyl bromide;...

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Product Details:

ETHYL 5-METHOXYINDOLE-2-CARBOXYLATE Basic information

Product Name:

ETHYL 5-METHOXYINDOLE-2-CARBOXYLATE

Synonyms:

5-methoxy-indole-2-carboxylicaciethylester;ethyl5-methoxy-2-indolecarboxylate;methoxy-5indolecarboxylated’ethyle-2;ETHYL 5-METHOXY-1H-INDOLE-2-CARBOXYLATE;ETHYL 5-METHOXYINDOLE-2-CARBOXYLATE;ETHYL 5-METHOXYL-1H-INDOLE-2-CARBOXYLATE;2-CARBETHOXY-5-METHOXYINDOLE;5-METHOXYINDOLE-2-CARBOXYLIC ACID ETHYL ESTER

CAS:

4792-58-9

MF:

C12H13NO3

MW:

219.24

EINECS:


Product Categories:

Indoles   and derivatives;Heterocyclic   Compounds;Building   Blocks;Heterocyclic   Building Blocks;Indoles

Mol File:

4792-58-9.mol

image001_副本.jpg

 

ETHYL 5-METHOXYINDOLE-2-CARBOXYLATE Chemical Properties 

form 

crystalline

color 

yellow to orange

Appearance:

yellow solid

Density:

1.216g/cm3

Melting Point:

154-157ºC

Boiling Point:

380.2ºC at 760mmHg

Flash Point:

183.7ºC

Refractive Index:

1.599

Storage   Condition:

-20ºC

Water Solubility 

Insoluble in water.

BRN 

178104

CAS DataBase Reference

4792-58-9(CAS DataBase Reference)

 

Safety Information 

Safety Statements 

22-24/25

WGK Germany 

3

RTECS 

NL6010000

HazardClass 

IRRITANT

Hs code

2933990090

 

ETHYL 5-METHOXYINDOLE-2-CARBOXYLATE Usage And Synthesis

Intermediate as

136816-75-6 Atevirdine, 130445-55-5 PIM-55

 

image003_副本.jpg

 

image005_副本.jpg

Synthesis route

image007_副本.jpg

1. WO2012/59776 A1; Page/Page column 57 ; WO 2012/059776 A1

2. Bioorganic and Medicinal Chemistry, vol. 5, # 3 p. 507 - 514

 

image009_副本.jpg

Reference:

Journal of Medicinal Chemistry, vol. 47, # 25 p. 6270 - 6282

 

image011_副本.jpg

Reference:

Organic Process Research and Development,   vol. 2, # 4 p. 214 - 220

 

 


ETHYL 5-METHOXYINDOLE-2-CARBOXYLATE Preparation   Products And Raw materials


Upstream information

Allyl bromide; Ethyl 5-Methoxyindole-2-Carboxylate; benzyl chloride; N-Methylformanilide; N,N-dimethylformamide;


Downtream information

ethyl 5-methoxy-3-(phenylhydrazinylidene)indole-2-carboxylate; 5-Methoxyindole; (3-diazonio-5-methoxyindol-2-ylidene)-ethoxymethanolate; ethyl 5-methoxy-1-prop-2-enylindole-2-carboxylate; N-hydroxy-5-methoxy-1H-indole-2-carboxamide; ethyl 1-benzyl-5-methoxyindole-2-carboxylate; 5-methoxy-1-methylindole-2-carboxylic acid; 5-Methoxy-1H-indole-2-carbonyl chloride; (5-Methoxy-1H-indol-2-yl)methanol; ethyl 5-hydroxy-1H-indole-2-carboxylate

  

Related Product Information:

3-HYDROXY-5-METHOXY-1H-INDOLE-2-CARBOXYLIC ACID ETHYL ESTER ETHYL 5-(TRIFLUOROMETHOXY)INDOLE-2-CARBOXYLATE 5-METHOXY-3-METHYL-1H-INDOLE-2-CARBOXYLIC ACID ETHYL ESTER ETHYL 5,6-DIMETHOXYINDOLE-2-CARBOXYLATE ETHYL 5-BENZYLOXYINDOLE-2-CARBOXYLATE AKOS JY2082684 Alpertine 1H-INDOLE-2-CARBOXYLIC ACID,5-ETHOXY-3-FORMYL-,ETHYL ESTER 3-AMINO-5,6-DIMETHOXY-1H-INDOLE-2-CARBOXYLIC ACID ETHYL ESTER 3-AMINO-5-METHOXY-1H-INDOLE-2-CARBOXYLIC ACID ETHYL ESTER AKOS JY2083359 5-ETHOXY-1H-INDOLE-2-CARBOXYLIC ACID ETHYL ESTER 3-DIMETHYLAMINOMETHYL-5-METHOXY-1H-INDOLE-2-CARBOXYLIC ACID ETHYL ESTER 3-(2-CHLORO-ACETYLAMINO)-5,6-DIMETHOXY-1H-INDOLE-2-CARBOXYLIC ACID ETHYL ESTER 3-(HYDROXY-PYRIDIN-2-YL-METHYL)-5-METHOXY-1H-INDOLE-2-CARBOXYLIC ACID PROPYL ESTER 3-FORMYL-5-METHOXY-1H-INDOLE-2-CARBOXYLIC ACID ETHYL ESTER AKOS JY2083451 AKOS JY2083221


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