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149104-88-1 4-(Methylsulfonyl)phenylboronic Acid

149104-88-1 4-(Methylsulfonyl)phenylboronic Acid

4-(METHYLSULFONYL)PHENYLBORONIC ACID Basic information 4-(METHYLSULFONYL)PHENYLBORONIC ACID Chemical Properties Safety Information 4-(METHYLSULFONYL)PHENYLBORONIC ACID Usage And Synthesis Upstream information 1,2-Dibromocyclopentene; 6-Bromopyridine-2-carbaldehyde; 2-Bromo-5-hydroxypyridine;...

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Product Details:

4-(METHYLSULFONYL)PHENYLBORONIC ACID Basic information

Product Name:

4-(METHYLSULFONYL)PHENYLBORONIC    ACID

Synonyms:

(4-methanesulfonylphenyl)boranediol;4-(Methylsulfonyl)phenylboronic    acid ,98%;4-[(Methylsulfonyl)phenylboronic    acid , May contain varying amounts of anhydride, 97%;4-(Methanesulfonyl)phenylboronic acid,4-(Methylsulfonyl)phenylboronic    acid;BP 14541    4-(METHANESULFONYL)PHENYLBORONIC ACID;4-Boronophenyl methyl sulphone;4-(Methanesulfonyl)phenylboronic Acid 4-(Methanesulfonyl)benzeneboronic    Acid;Boronic acid,    B-[4-(Methylsulfonyl)phenyl]-

CAS:

149104-88-1

MF:

C7H9BO4S

MW:

200.02

EINECS:

1592732-453-0

Product Categories:

B(Classes of Boron Compounds);Boronic Acids & Esters;Phenyls & Phenyl-Het;Boronate  Ester;Potassiu Trifluoroborate;blocks;BoronicAcids;Boronic Acids & Esters;Phenyls & Phenyl-Het;Boronic acids;Boronic Acid;Aryl;Organoborons;Sulfonyl

Mol File:

149104-88-1.mol

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4-(METHYLSULFONYL)PHENYLBORONIC ACID Chemical Properties

Melting point 

275-277 °C

form 

Powder

color 

Off-white

Appearance:

Off-white powder

Density:

1.39g/cm3

Boiling    Point:

445.5ºC at 760mmHg

Flash    Point:

223.2ºC

Refractive Index:

1.566

Storag Condition:

0-6ºC

Vapor Pressure:

1.02E-08mmHg at 25°C

CAS DataBase Reference

149104-88-1(CAS    DataBase Reference)


Safety Information

Hazard Codes 

Xi

Risk Statements 

36/37/38

Safety Statements 

37/39-26-24/25-22

Hazard Note 

Irritant

HazardClass 

IRRITANT


4-(METHYLSULFONYL)PHENYLBORONIC ACID Usage And Synthesis

Chemical Properties

Off-white powder

Uses

suzuki reaction

Uses

4-(Methylsulfonyl)phenylboronic    Acid is a heteroaryl boronic acid that was tested for their in vitro    hormone-sensitive lipase inhibitory properties.

Intermediate as

603139-19-1 Odanacatib (MK-0822)    and 1418013-75-8 NMS 873

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Synthesis route

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Reference:

Journal of Organic Chemistry, , vol. 73, # 12    p. 4662 - 4670


Upstream information

1,2-Dibromocyclopentene; 6-Bromopyridine-2-carbaldehyde; 2-Bromo-5-hydroxypyridine; 4-(METHYLSULFONYL)PHENYLBORONIC ACID; 4-Bromophenol; 1-Bromo-4-iodobenzene; 4'-Bromo-2,2,2-trifluoroacetophenone; trifluoro(4-(methylsulfonyl)phenyl)borate; 3-Bromobenzaldehyde;


Downtream information

2,2,2-Trifluoro-1-[4'-(methylsulfonyl)-4-biphenylyl]ethanone; 3-[3-(Cyclopentylsulfanyl)-5-({[2-methyl-4'-(methylsulfonyl)-4-bi phenylyl]oxy}methyl)-4H-1,2,4-triazol-4-yl]pyridine; 1-(4-bromophenyl)-4-methylsulfonylbenzene; 6-(4-methylsulfonylphenyl)pyridine-2-carbaldehyde; 4-(4-methylsulfonylphenyl)phenol; 6-(4-(Methylsulfonyl)phenyl)pyridin-3-ol; 3-(4-methylsulfonylphenyl)benzaldehyde; 1-azido-4-methylsulfonylbenzene; 1-(2-bromocyclopenten-1-yl)-4-methylsulfonylbenzene; 4-(METHYLSULFONYL)PHENYLBORONIC ACID

 

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