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87199-16-4 3-Formylphenylboronic Acid

87199-16-4 3-Formylphenylboronic Acid

3-Formylphenylboronic acid Basic information 3-Formylphenylboronic acid Chemical Properties Safety Information 3-Formylphenylboronic acid Usage And Synthesis 3-Formylphenylboronic acid Preparation Products And Raw materials Upstream information magnesium compound of...

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Product Details:

3-Formylphenylboronic acid Basic information

Product Name:

3-Formylphenylboronic    acid

Synonyms:

3-Formylpenylboronic Acid;Boronic acid,    (3-formylphenyl)- (9CI);3-FORMYLPHENYLBORONIC    ACID (CONTAINS VARYING AMOUNTS OF ANHYDRIDE);3-(Dihydroxyboryl)benzaldehyde,    3-Boronobenzaldehyde;3-Formylphenylboronic    acid,97%;2-bromo-1-(2,3-dihydrobenzo[b][1,4]dioxin-6-yl)ethanone;3-Formylphenylboronic acid, May contain varying amounts    of anhydride, 97%;3-Formylphenylboroni

CAS:

87199-16-4

MF:

C7H7BO3

MW:

149.94

EINECS:

 

Product Categories:

ALDEHYDE;Aldehydes;blocks;BoronicAcids;Boronic Acid series;Boron, Nitrile, Thio,& TM-Cpds;Carbonyl Compounds;Substituted Boronic Acids;Boronic Acids & Esters;Phenyls & Phenyl-Het;Boronic acids;Boronic Acid;Aryl;Organoborons;B (Classes of Boron Compounds);Boronic Acids & Esters;Phenyls & Phenyl-Het;Aryl Boronic Acids;Boronic Acids and Derivatives;Building Blocks;C7;Chemical Synthesis;Monosubstituted Aryl Boronic Acids;Organic Building Blocks;Organometallic Reagents;Boronate Ester;Potassium Trifluoroborate

Mol File:

87199-16-4.mol

image001.gif


3-Formylphenylboronic acid Chemical Properties

Melting point 

182-186 °C

storage temp. 

0-6°C

form 

Powder, Crystals, and/or Chunks

color 

Off-white to beige or light orange

Sensitive 

Air Sensitive

Appearance:

off-white cryst

Density:

1.244g/cm3

Boiling Point:

354.388ºC at 760 mmHg

Flash Point:

168.128ºC

Refractive Index:

1.548

Storage Condition:

0-6ºC

BRN 

3030769

CAS DataBase Reference

87199-16-4(CAS    DataBase Reference)


Safety Information

Hazard Codes 

C,Xi

Risk Statements 

34-36/37/38

Safety Statements 

22-26-36/37/39-45-37/39-27

RIDADR 

UN 3261 8/PG 3

WGK Germany 

3

Hazard Note 

Irritant

HazardClass 

IRRITANT, MOISTURE SENSITIVE

PackingGroup 

hazard declaration:

H314

HS Code:     

2931900090


3-Formylphenylboronic acid Usage And Synthesis

Chemical Properties

Off-white Cryst

Uses

Reagent used: • ;To study the effects of boronic acid on fluoride-selective chemosignaling behavior of merocyanine dye1• ;As exciton-coupled CD probes for epigallocatechin gallate2Biological inhibitor of γ-glutamyltranspeptidase3Reactant involved in: • ;Palladium-catalyzed homocoupling4• ;Suzuki coupling reactions5

Uses

suzuki reaction

Intermediate as

912545-86-9(free base) SAG

image003_副本.jpg

Synthesis route

image005_副本.jpg

Reference:

Meudt, Andreas; Scherer, Stefan; Vollmueller,    Frank; Erbes, Michael Patent: US2004/49050 A1, 2004

image007_副本.jpg

Reference:

TEIJIN LIMITED Patent: EP1460059 A1, 2004 ;    Location in patent: Page 9

image009_副本.jpg

Reference:

Arkiv foer Kemi, , vol. 10, p. 507,509

image011_副本.jpg

Reference:

Journal of the American Chemical Society, ,    vol. 134, # 28 p. 11667 - 11673

image013_副本.jpg

Reference:

Chemical Communications, , vol. 46, # 15 p.    2677 - 2679


3-Formylphenylboronic acid Preparation Products And Raw materials

Preparation Products

3-(4-METHYLPHENYL)BENZALDEHYDE


Upstream information

magnesium compound of 3-(dimethoxymethyl)bromobenzene; 9,10-Dibromoanthracene; 9-Bromoanthracene; 2-Hydroxy-4-iodobenzoic acid; phenol; 2-Amino-3-Chlorothiophenol; 2-Chloropyrimidine; Iodobenzene; tris(3-methylphenyl)-1,3,5,2,4,6-trioxatriborinane; 2-Bromopyrimidine;


Downtream information

3-(2-FURYL)BENZALDEHYDE; 3-Phenylbenzaldehyde; 3-(2-Pyridyl)benzaldehyde; 4-(3-formylphenyl)benzonitrile; 3-(2-Methylnaphthalen-1-yl)benzaldehyde; 3-(3-Methoxypyridin-2-yl)benzaldehyde; {2',6'-Dimethyl-4'-[3-(methylsulfonyl)propoxy]-3-biphenylyl}metha nol; 3-Naphthalen-1-yl-benzaldehyde; 3-Fluorobenzaldehyde; 3-thiophen-2-ylbenzaldehyde;


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