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87199-18-6 3-Hydroxybenzeneboronic Acid

87199-18-6 3-Hydroxybenzeneboronic Acid

3-Hydroxyphenylboronic acid Basic information 3-Hydroxyphenylboronic acid Chemical Properties Safety Information 3-Hydroxyphenylboronic acid Usage And Synthesis Upstream information 2-bromopyridine; 2,3-dimethylbutane-2,3-diol; 3-aminophenylboronic acid; trimethyl borate; 4-Bromophenol;...

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Product Details:

3-Hydroxyphenylboronic acid Basic information

Product Name:

3-Hydroxyphenylboronic acid

Synonyms:

3-Hydroxyphenylboronic Acid    (contains varying amounts of Anhydride); 3-Hydroxyphenylboronic acid, 3-Hydroxyphenylboronic acid; 3-Hydroxyphenylboronic acid, May    contain varying amounts of anhydride; m-Hydroxybenzeneboronic acid; 3-Hydroxyphenylboronic acid; B-(3-hydroxy-phenyl)boronic acid; 3-Hydroxybenzeneboronic Acid; 3-Boronophenol

CAS:

87199-18-6

MF:

C6H7BO3

MW:

137.93

EINECS:

 

Product Categories:

Aryl; Organoborons; B (Classes of Boron Compounds); Boronic Acids; Boronic Acids & Esters; Phenyls & Phenyl-Het; Boronic Acids; Boronic Acids and Derivatives; Boronate Ester; Potassium Trifluoroborate; blocks; Boronic Acids; Substituted Boronic Acids; Boronic Acids & Esters; Phenyls & Phenyl-Het; Organic acids;
Boronic Acid


3-Hydroxyphenylboronic acid Chemical Properties

Melting point 

210-213 °C (dec.)(lit.)

form 

Crystalline Powder, Crystals    and/or Chunks

color 

Pink to gray to tan

Properties

white to light yellow crystal    powder

BRN 

3240771

Density:

1.32 g/cm3

Melting Point:

210-213ºC

Boiling Point:

370ºC at 760    mmHg

Flash Point:

177.6ºC

Refractive Index:

1.582

CAS DataBase Reference

87199-18-6(CAS DataBase Reference)


Safety Information

Hazard Codes 

Xi

Risk Statements 

36/37/38-22

Safety Statements 

37/39-26-36/37/39

WGK Germany 

3

Hazard Note 

Irritant

HazardClass 

IRRITANT


3-Hydroxyphenylboronic acid Usage And Synthesis

Uses

suzuki reaction

Intermediate as

546141-08-6 URB597, 1431985-92-0    K02288, 395104-30-0 CC401 and 887264-45-1 JP104
     

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Synthesis route

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Reference:

Brown, William; Walpole, Christopher; Wei,    Zhongyong Patent: US2003/187022 A1, 2003

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Reference:

Journal of the American Chemical Society, ,    vol. 54, p. 4415,4418

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Reference:

Journal of the American Chemical Society, ,    vol. 54, p. 4415,4418

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Reference:

Journal of the American Chemical Society, ,    vol. 134, # 28 p. 11667 - 11673


Upstream information

2-bromopyridine ; 2,3-dimethylbutane-2,3-diol; 3-aminophenylboronic acid ; trimethyl borate ; 4-Bromophenol ; 3-Bromobenzamide ; S-(Trifluoromethyl) dibenzothiophenium trifluoromethanesulfonate ; 3-Bromobenzonitrile ; 9'-diethylamino-3'-bromobenzo[a]fluoran ; 3-Bromobenzyl alcohol;

 

Downtream information

[3-[4-(3-boronophenoxy)carbonylbenzoyl]oxyphenyl]boronic acid ; potassium,trifluoro-(3-hydroxyphenyl)boranuide ; 3'-Hydroxy-[1,1'-biphenyl]-3-carboxamide ; 3-Hydroxyphenylboronic acid ; 3-[3-(hydroxymethyl)phenyl]phenol ; 9'-(diethylamino)spiro[2-benzofuran-3 , 12'-benzo[a]xanthene]-1-one;biphenyl-3-ol ; 3-[2-(5-ethyl-3 , 4-diphenylpyrazol-1-yl)phenyl]phenol ; [3-(2,6-dichlorobenzoyl)oxyphenyl]boronic acid ; 3-(2-methoxyphenyl)phenol

 

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